Status : Verified
Personal Name Ramos, Ma. Louise Margaret A.
Resource Title Graphene - modified concrete: Its properties and microstructure
Date Issued 27 June 2019
Abstract The properties of concrete are known to be very dependent on its microstructure. By altering this
microstructure, the strength and capacity of concrete may be enhanced. In this research, a constant
concentration of graphene nanoplatelets (GNP) by weight of cement were added into the usual
concrete mix, at varying water-to-cement ratios, to evaluate its effect on the mechanical and
transport properties and investigate the changes in its microstructure. The potential of incorporating
GNP in concrete was evident from the enhancements obtained particularly for those samples with
low water-to-cement ratio. The hydration of the concrete samples was observed to accelerate which
may be verified from the gathered increases on their early strengths. This accelerated hydration was
proven by the graphs generated from Thermogravimetric Analysis (TGA) and Fourier-Transform
Infrared Spectroscopy (FTIR) wherein no significant increases on the final amount of hydration
products were recorded. For samples with high water-to-cement ratio, porosity increased, implying
that graphene nanoplatelets may cause formation of a poorer pore structure. Likewise, its resistance
to chloride penetration was observed to improve only for those samples with low water-to-cement
ratio. Photos from Scanning Electron Microscope (SEM) confirmed that addition of GNP in a
matrix with high water content may increase the volume of pores present in the concrete structure
as these nanoplatelets tend to crumple or fold. For low water contents, on the other hand, addition
of GNP increased the strength properties and improved the durability of concrete samples by
demonstrating their ability to mitigate initiation of cracks and fill in pores as they tend to form a
link in between, thus, promoting a denser structure and an efficient distribution of stresses inside
the matrix
Degree Course Master of Science in Civil Engineering (Structural)
Language English
Keyword Graphene, Mechanical Properties, Transport Properties, Microstructure
Material Type Thesis/Dissertation
Preliminary Pages
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